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Picosecond flash photolysis and spectroscopy: 3,3′-diethyloxadicarbocyanine iodide (DODCI)

✍ Scribed by Douglas Magde; Maurice W. Windsor

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
833 KB
Volume
27
Category
Article
ISSN
0009-2614

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✦ Synopsis

We dcmonstratc transient absorption spectroscopy with picosecond time resolution and nanomctcr spectral rcsolution over the entire visible region. To resolve mu1 tiple discrepancies in the literature, we studied 3,3'-dicrhyloxadicarbocyanine iodide. We measured both cscited sinflct liFerime and ground sure deplaion and recovery. The kinetics of the two Processes are the same. The characteristic time is 1.15 f 0.15 nsec in ethanol and 560 + 70 pscc in waler. WC report lluorcscence yield dererminntions and comment on the controversy over photoisomer generation.

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