.pi. Participation and exo-endo rate ratios in the solvolysis of methoxy- and nitro-substituted benzonorbornen-2-yl derivatives
β Scribed by Brown, Herbert C.; Tritle, Gary L.
- Book ID
- 126440356
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 342 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Abstract The solvolysis rates and products of the 6β__exo__βsubstituted 2β__exo__β **1a**β**1u**, and 2β__endo__βnorbornyl __p__βtoluenesulfonates **2a**β**2u**, have been determined. In general, the rate constants for **1** and **2** (log __k__) correlate well with the inductive constants Ο of
## Abstract The solvolysis rate constants __k__ for the 6β__endo__βsubstituted 2β__exo__βnorbornyl toluenesulfonates **7** have been determined. Values of log__k__ correlate well with the respective inductive constants of the substitutents except when the latter are nucleophilic and therefore lead