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.pi. Participation and exo-endo rate ratios in the solvolysis of methoxy- and nitro-substituted benzonorbornen-2-yl derivatives

✍ Scribed by Brown, Herbert C.; Tritle, Gary L.


Book ID
126440356
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
342 KB
Volume
90
Category
Article
ISSN
0002-7863

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## Abstract The solvolysis rates and products of the 6‐__exo__‐substituted 2‐__exo__‐ **1a**‐**1u**, and 2‐__endo__‐norbornyl __p__‐toluenesulfonates **2a**‐**2u**, have been determined. In general, the rate constants for **1** and **2** (log __k__) correlate well with the inductive constants Οƒ of

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