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Physicochemical properties of RuO 2 and IrO 2 electrodes affecting chlorine evolutions

โœ Scribed by Le Luu, Tran ;Kim, Jiye ;Yoon, Jeyong

Book ID
122296223
Publisher
Elsevier
Year
2015
Tongue
English
Weight
359 KB
Volume
21
Category
Article
ISSN
1226-086X

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A consideration of the activation energy
A consideration of the activation energy for the chlorine evolution reaction on RuO2 and IrO2 electrodes
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Aba&act -The electrocatalysis for the chlorine evolution reaction on RuOs and Ir02 electrodes was &US& on the ba.& of& activation energy. The activated complex with the pentagonal bipyramid-type structure was speculated to be formed in the transition state for the Heymvsky reaction. The activation e

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H, evolution from acid solutions has been studied on IrO, + RuO, electrodes over the whole oxide composition range. Kinetics has been investigated by means of cyclic voltammetry, quasistationary current-potential curves and reaction order determination. Results have shown that the Tafel slope for as

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Chlorine and oxygen evolution on various compositions of RuO2/TiO2 electrodes
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## Thechlorine and oxygen evolution reactions have been investigated on various compositions of Ti supported Ru0,/Ti02 anodes. Conclusions have been reached on the structure of the electrode, and its influence on the mechanism of these two reactions, at the different compositions of Ru0JI'i02.