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Physical Organic Chemistry of Transition Metal Carbene Complexes. 7. 1 Kinetics of Hydrolysis of (CO) 5 MC(OR)Ph (M = Cr, W; R = Me, Et) and (CO) 5 Cr(OMe)CHCHPh in Aqueous Acetonitrile

✍ Scribed by Bernasconi, Claude F.; Flores, Francis X.; Kittredge, Kevin W.


Book ID
126087808
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
430 KB
Volume
119
Category
Article
ISSN
0002-7863

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Physical Organic Chemistry of Transition
✍ Claude F. Bernasconi; Christina Whitesell; Rebecca A. Johnson πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 165 KB

AbstractÐA kinetic study of the reactions of (CO) 5 CrvC(OMe)C 6 H 4 X (X4-Cl, 4-F, H, 4-Me, 4-OMe and 4-NMe 2 ) and the respective tungsten carbene complexes with primary aliphatic amines (mainly n-butylamine) in 50% MeCN±50% water (v/v) at 258C is reported. The rate law is complex and shows OH 2 a