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Physical Organic Chemistry of Transition Metal Carbene Complexes. 5. Kinetics and Mechanism of Hydrolysis of (CO)5Cr:C(OCH3)CH3 and (CO)5Cr:C(OCH2CH3)CH3 in Aqueous Acetonitrile

โœ Scribed by Bernasconi, Claude F.; Flores, Francis X.; Sun, Weitao


Book ID
125973997
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
649 KB
Volume
117
Category
Article
ISSN
0002-7863

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Coordinatedversus Noncoordinated Isocyan
โœ Ekkehardt Hahn, F. ;Tamm, Matthias ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 246 KB ๐Ÿ‘ 1 views

The triisocyanide ligand CH3C(CH2NC)3 reacts with Cr-acterized by an X-ray structure analysis allowing a direct com-(CO),(THF) depending on the stoichiometry to give the com-parison of the bonding parameters of coordinated and nonplexes CH3C(CH2NC),[CH2NC ~ Cr(C0)5]3-, (x = 1, 2). The coordinated is