Phthalocyaninatoiron complexes with tridentate ligands
β Scribed by M Hanack; M Fiedler; L.R Subramanian
- Book ID
- 117541956
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 260 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0379-6779
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π SIMILAR VOLUMES
Recent EXAFS [l] studies of nitrogenase and other molybdo-proteins have stimulated interest in molybdenum complexes with sulfur ligands. However, none of the complexes so far reported bind or activate dinitrogen. In fact, there are very few examples of molybdenum-sulfur complexes which interact with
The complexes of formula [ Fe ( Pc )( diazole )~2~]Β·n H ~2~ O ( Pc = phthalocyaninato dianion ; diazole = pyrazole , 3(5)-methylpyrazole, indazole and 1-phenylimidazole) have been prepared and characterized. The MΓΆssbauer spectra of the bisadducts of [ Fe ( Pc )] with diazoles show values of isomer