Complexes of phthalocyaninatoiron(II) with diazoles

✍ Scribed by R. Ettorre; D. Marton; U. Russo; P. Zanonato

• Book ID: 102398865
• Publisher: John Wiley and Sons
• Year: 2001
• Tongue: English
• Weight: 53 KB
• Volume: 05
• Category: Article
• ISSN: 1088-4246
• DOI: 10.1002/jpp.356

✦ Synopsis

The complexes of formula [ Fe ( Pc )( diazole )~2~]·n H ~2~ O ( Pc = phthalocyaninato dianion ; diazole = pyrazole , 3(5)-methylpyrazole, indazole and 1-phenylimidazole) have been prepared and characterized. The Mössbauer spectra of the bisadducts of [ Fe ( Pc )] with diazoles show values of isomer shift close to those of the corresponding complexes with pyridines, but somewhat smaller values of quadrupole splitting.