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Photostimulated reaction of 1-iodoadamantane with carbanionic nucleophiles in DMSO by the SRN1 mechanism

✍ Scribed by Borosky, Gabriela L.; Pierini, Adriana B.; Rossi, Roberto A.

Book ID
111944569
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
352 KB
Volume
55
Category
Article
ISSN
0022-3263

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Reactions of N-thioacetylmorpholine anio
Reactions of N-thioacetylmorpholine anion with iodoarenes and 1-iodoadamantane by the SRN1 mechanism
✍ Marcelo C MurguΓ­a; Roberto A Rossi πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 204 KB

The ~afion of N-acetylthiomorpholinΒ’ 2 was studied in photostimdated reactions with iodobenzene la and l-iodonaphthalene lb in DMSO, giving good yields of the substitution products 3a and 3b by the SR~I mechanism. The reaction of la with 2 is also induced with FeBr2. l-Iodoadamantane 4 did not react