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Reactions of N-thioacetylmorpholine anion with iodoarenes and 1-iodoadamantane by the SRN1 mechanism

✍ Scribed by Marcelo C Murguía; Roberto A Rossi

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
204 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

The ~afion of N-acetylthiomorpholin¢ 2 was studied in photostimdated reactions with iodobenzene la and l-iodonaphthalene lb in DMSO, giving good yields of the substitution products 3a and 3b by the SR~I mechanism. The reaction of la with 2 is also induced with FeBr2. l-Iodoadamantane 4 did not react w~ the anion of N-acetylmotpholine, but reacted with 2 to give the substitution product 5 under irradiation. By competition experiments, acetophenune enolate ions are 1.4 times more reactive than 2 toward la and 3.3 times toward 4.

📜 SIMILAR VOLUMES

ChemInform Abstract: Reactions of the N-
ChemInform Abstract: Reactions of the N-Thioacetylmorpholine Anion with Iodoarenes and 1- Iodoadamantane by the SRN1 Mechanism.
✍ M. C. MURGUIA; R. A. ROSSI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

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