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Photosensitized decarboxylative Michael addition through N-(acyloxy)phthalimides via an electron-transfer mechanism

โœ Scribed by Okada, Keiji; Okamoto, Kazushige; Morita, Naoto; Okubo, Katsura; Oda, Masaji


Book ID
127089428
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
272 KB
Volume
113
Category
Article
ISSN
0002-7863

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9,10-Dicyanoanthracene (DCA) photosensitizes the oxidation of a series of para substituted aryl alkanols in oxygen-saturated acetonitrile. Product analysis and Hammett correlations support an electron transfer mechanism for the title reaction.