𝔖 Bobbio Scriptorium
✦   LIBER   ✦

9,10-Dicyanoanthracene photosensitized oxidation of aryl alkanols: evidence for an electron transfer mechanism

✍ Scribed by Ioannis N. Lykakis; Stellios Lestakis; Michael Orfanopoulos

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
248 KB
Volume
44
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

9,10-Dicyanoanthracene (DCA) photosensitizes the oxidation of a series of para substituted aryl alkanols in oxygen-saturated acetonitrile. Product analysis and Hammett correlations support an electron transfer mechanism for the title reaction.

πŸ“œ SIMILAR VOLUMES

Reduction of a ketone by lithium diisopr
Reduction of a ketone by lithium diisopropyl amide evidence for an electron-transfer mechanism
✍ Lawrence T. Scott; Kevin J. Carlin; Thomas H. Schultz πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 100 KB

The widespread use of lithium diisopropyl amide (LDA) as a strong base has revolutionized numerous facets of mechanistic and synthetic organic chemistry in recent years;' however, it is less widely appreciated that amide bases can function also as reducing agents.' LDA, for example, reduces benzophe

Direct evidence for an electron transfer
Direct evidence for an electron transfer mechanism in the reactions of lithium thioalkoxides with organic substrates
✍ E.C. Ashby; A.B. Goel; W.S. Park πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 236 KB

The degree of polar and radical character exhibited in reactions of metal alkyls, metal hydrides and typical nucleophiles (M-Y, where Y = OR, SR and NR2) with various organic substrates has been the subject of considerable interest for several years. 1-3 The mechanisms of these reactions have been p