We have reported that aliphatic amines are efficient photoreducing agents for aromatic ketones (l-4) which have low-lying n,rrY triplet states. ( ) We have also found that p-aminobenzophenone, PAB, which is not photoreduced by 2-propanol because of a low-lying chemically unreactive 'rr,rrW or charge
Photoreduction of fluorenone by amines: catalysis by thiol
β Scribed by PaulG. Stone; SaulG. Cohen
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 80 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0047-2670
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The reaction of triplet benzophenone with the tertiary amines triisopropylamine and diisopropyl-3-pentylami~e does not lead to photoreduction. An explanation of this unusual behaviour is given based on the particular structure of these amines. The initial charge transfer events are compared with tho
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v