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Photoredox behaviour of chlorocopper(II) complexes in acetonitrile: mechanism and quantum yields

✍ Scribed by E. Cervone; F. Diomedi Camassei; I. Giannini; J. Sykora

Book ID: 103495004
Publisher: Elsevier Science
Year: 1979
Weight: 951 KB
Volume: 11
Category: Article
ISSN: 0047-2670
DOI: 10.1016/0047-2670(79)85021-2

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The electron transfer step of the reduction of Mn(acac)s and Co(acac)s by Fe(I1) in acetonitrile is preceded by the one-ended dissociation of an acac ligand and the formation of a binuclear bridged complex. After the electron transfer has taken place through the bridging ligand, the complex dissocia