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Photochemical and thermal behaviour of isocyanide complexes: II. Photolysis of Fe(bpy)2(CNCH3)2(BF4)2 in acetonitrile

✍ Scribed by L.L. Costanzo; S. Giuffrida; G. De Guidi; G. Condorelli


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
558 KB
Volume
273
Category
Article
ISSN
0022-328X

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The electrochemistry of ~i("'(bpy), (ClOJ,] in acetonitrile has been re-examined using rotating disc and ring-disc electrode techniques. Based on the results of these experiments a consistent scheme for the coupled electron transfer and ligand exchange reactions is proposed.