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Photorearrangements of bicyclo[3.2.1]oct-2-en-7-ones. A substituent effect study. Mechanistic studies in photochemistry. 19

✍ Scribed by Givens, Richard S.; Chae, Woo Ki

Book ID: 126939648
Publisher: American Chemical Society
Year: 1978
Tongue: English
Weight: 401 KB
Volume: 100
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00487a078

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## Abstract Orientation effects of electronegative substituents on vicinal carbon‐proton coupling constants are studied in 1,2‐disubstituted propanes and are found to resemble those on vicinal proton‐proton coupling constants. Known relations for the orientation effect of substituents on synclinal