Photoreactions of aromatic compounds—XXIX : Pathway and intermediates of the photoreactions of 3,5-dinitroanisole with nucleophiles
✍ Scribed by G.P. de Gunst; E. Havinga
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 354 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Reaction of nitric acid vlth unsaturated steroids under mild conditions Is known for a very long time and several authors have carried aut this reaction to prepare nltrosterolds l-3. In aw hands this reaction yielded a novel pro&et whose structure and mode of formation Is now elucidated.
The results described here demonstrate once again the decisive influence of the metal upon the reactivity and selectivity of even so-called polar organometallic or "carbanion" derivatives. Access to both diastereomers of products of type 2 and 3 is not only interesting in itself, but should provide