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Photoreaction of Biacetyl and 1,3-Dioxole Derivatives: Modification of the Mechanism of the Photoreaction of Carbonyl Compounds with Electron-Rich Olefins

✍ Scribed by Dr. Jochen Mattay; Dipl.-Chem. Joachim Gersdorf; Dr. Hans Leismann; Dr. Steen Steenken

Publisher: John Wiley and Sons
Year: 1984
Tongue: English
Weight: 212 KB
Volume: 23
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198402491

No coin nor oath required. For personal study only.

✦ Synopsis

The results described here demonstrate once again the decisive influence of the metal upon the reactivity and selectivity of even so-called polar organometallic or "carbanion" derivatives.

Access to both diastereomers of products of type 2 and 3 is not only interesting in itself, but should provide selective routes to isoquinoline alkaloids with a-hydroxylated side chains in the 1-position["].

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