Photophysical and redox properties of water-soluble porphyrins in aqueous media
β Scribed by Kalyanasundaram, K.; Neumann-Spallart, M.
- Book ID
- 120034154
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 866 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
Water-soluble ytterbium complex of tetra-p-sulfonatophenylporphyrin (H,TPPS) with the formulation of Yb TPPS OH . 2 im 3H,O (im = imidazole), stable in pH 2 5 solution, has been synthesized and characterized by elemental analysis, IR and UV-visible spectra. The structural formula of this ytterbium p
these coordination compounds. Deviating from the photochemistry of the regular (coplanar) metalloporphyrins, the out-of-plane structure and the kinetic lability of the SAT complexes facilitate the photodissociation as well as the separation of the primary products of the photoinduced LMCT reaction,