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Photophysics and photochemistry of kinetically labile, water-soluble porphyrin complexes

✍ Scribed by Ottó Horváth; Róbert Huszánk; Zsolt Valicsek; György Lendvay

Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
475 KB
Volume
250
Category
Article
ISSN
0010-8545

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✦ Synopsis

these coordination compounds. Deviating from the photochemistry of the regular (coplanar) metalloporphyrins, the out-of-plane structure and the kinetic lability of the SAT complexes facilitate the photodissociation as well as the separation of the primary products of the photoinduced LMCT reaction, promoting an irreversible ring-opening of the oxidized porphyrin.

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