✦ LIBER ✦

Photophysical and electrochemical characterization of PdII cyclometallated complexes with 2-acetylpyridine-phenylhydrazone

✍ Scribed by Gabriel García-Herbosa; Asunción Muñoz; Mauro Maestri

Book ID: 103994221
Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 559 KB
Volume: 83
Category: Article
ISSN: 1010-6030
DOI: 10.1016/1010-6030(94)03813-9

No coin nor oath required. For personal study only.

✦ Synopsis

The absorption spectra, emission spectra, emission lifetimes and photochemical and electrochemical behaviour of six monomeric cyclometallated complexes [Pd(CNN)X14+ (where CNN is the C-deprotonated form of 2acetylpyridine-phenylhydrazone and X is I-, Cl-, CMepy, PPh,, P(QPh), P(OMe),) and two dimeric cyclometallated complexes [(CNN)Pd(XX)Pd(NNC)]*' (where XX is 4,4'-bipyridine (4,4'-bpy) or bis(diphenylphosphino)methane (dppm)) were studied. The relatively intense absorption band exhibited by the complexes at 450 nm and the luminescence emission observed at 298 and 77 K were assigned to in&a&and (IL) transitions with remarkable charge transfer character (ILCT).

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