𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Photooxidations of 1,1-dialkyl-2-arylhydrazines by single electron transfer

✍ Scribed by Clotilde Ferroud; Guillaume Cocquet; Alain Guy

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
224 KB
Volume
40
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

The oxidation of substflu~d hydrazines through moneelec~dc transfer leads re~o-and stercoselectivcly with good yiclds to a.hydrazinom" trilcs under nuld con~ftons.

πŸ“œ SIMILAR VOLUMES

Reduction of Ag(I) by 1-acyl-2-arylhydra
Reduction of Ag(I) by 1-acyl-2-arylhydrazines: Mechanism of photographic infectious development
✍ W. Russell Bowman; J. Anthony Forshaw; Kevin P. Hall; Jonathan P. Kitchin; Andre πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 French βš– 887 KB

The photographic process of 'infectious development' in which l-acyl-2-arylhydrazines reduce AgO) has been studied using analogues. 1-Acyl-2-aryldiazenes, resulting from oxidation of 1-acyl-2-arylhydrazines, are hydrolysed to anions of aryldiazenes (ArN=NH), which undergo further oxidation with loss

Aliphatic 1,2,3-Triketones by Ozonolysis
Aliphatic 1,2,3-Triketones by Ozonolysis of Dialkyl-1,4-benzoquinones
✍ Prof. Dr. Gottfried Schill; Dipl.-Chem. Enno Logemann; Dipl.-Chem. Clemens ZΓΌrch πŸ“‚ Article πŸ“… 1972 πŸ› John Wiley and Sons 🌐 English βš– 123 KB πŸ‘ 1 views

distillation under high vacuum at room temperature (time required ca. 48 h). Double recrystallization of the residue from pentane afforded (2) in 50 to 55% yield (based on ( I ) ) . For conversion of (2) into (3) a solution of (2) (2.3 mmol) and Fe(CO), (3 ml) in ether (50 ml) was irradiated at -40