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Formation of a 1,2-dioxane by electron-transfer photooxygenation of 1,1-di(p-anisyl)ethylene

✍ Scribed by Klaus Gollnick; Albert Schnatterer


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
224 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


A new mode of electron-transfer photooxygenation is shown to occur with the title compound (4). CCA-sensitize.tion _ With this electron-rich ethylene derivative,


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Electron-transfer photooxygenation of l-butyl-2,3\_diphenylaziridine with 9,10dicyanoanthracene in oxygen-saturated acetonitrile yields 4-butyl-3,5-diphenyl-1,2,4dioxazolidine. This peroxide is surprisingly stable in nonpolar solvents decomposing to benzaldehyde and N-butylbenzamide upon heating to