Photooxidation of 2,5-Dimethyl-2,3,4-hexatriene—Matrix Isolation of a Trisdioxetane
✍ Scribed by Dr. Wolfram Sandar; Andreas Patyk
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- English
- Weight
- 352 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0044-8249
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## Abstract The isolation and structure determination of a new microbial product, (+)‐ (123/45)‐2,3,4,5‐tetrahydroxy‐1‐cyclohexanemethanol is described. This product was detected in the fermentation broth of a newly isolated actinomycete by its antibacterial activity. A novel isolation method was d
The [Co(PF3)4]0 anion can be precipitated from aqueous solutions with voluminous cations. During the conversion of HCo(PF3)d into [Co(PF3)4]0, a bathochroniic shift of the P-F valence vibrations is observed which is probably due to a reduction in the double-bond character of the P-F bond. At PF3-pr
study ( < -30"C)1111. This is best evidenced by the upfield shift of protons H' (by 23Hz) and H5 (by 32Hz) on going from ( 3 ) to ( 5 ) , which simply reflects the increased availability of the lone pair for limited delocalization but is clearly inconsistent with the development of the diamagnetic r