Photolytische und thermische Umsetzungen von μ3-As[WCp(CO)2]3 mit Fe(CO)5 und Fe2(CO)9; Röntgenstrukturanalysen der Cluster FeW2Cp2(CO)7[μ3-As–WCp(CO)3], Fe2WCp(CO)8H[μ3-As – WCp(CO)3] und Fe2WCp(CO)8H[μ3-As–FeCp(CO)2]

✍ Scribed by Caballero, Celia ;Lehne, Dieter ;Nuber, Bernhard ;Ziegler, Manfred L.

• Publisher: Wiley (John Wiley & Sons)
• Year: 1991
• Tongue: English
• Weight: 592 KB
• Volume: 124
• Category: Article
• ISSN: 0009-2940
• DOI: 10.1002/cber.19911240604

✦ Synopsis

Photolytic and Thermic Reactions of p,-As[WCp(CO),], with Fe(CO)5 and Fez(CO)*; X-Ray Structure Analyses of the Clusters FeW2Cp2(C0),[p3-As -WCp(CO),], FezWCp(CO)8H@3-As -WCp(CO),], and Fe2WCp(C0)8H[p3-As -FeCp(CO),] p3-As[WCp(C0)2]3 (1) (Cp = C5H,) reacts with Fe(C0)5 pho-compound Fe2WCp(CO)8H[p3-As -FeCp(CO)2] (7) besides 5 tolytically and thermically to yield FeW2Cp2(C0)&-and 6. The products have been characterized by spectroscopic ~ ~ ,