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Photolytic degradation of fluoroquinolone carboxylic acids in aqueous solution

✍ Scribed by Jürgen Burhenne; Marc Ludwig; Michael Spiteller


Publisher
Springer-Verlag
Year
1997
Tongue
English
Weight
532 KB
Volume
4
Category
Article
ISSN
0944-1344

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Poly(acry1ic acid) (PAA) was decarboxylated in aqueous solution as a function of pH and ionic strength in the temperature range 10O-35O0C. Degradation kinetics were first order with respect to acid functionality. The rate of decarboxylation at high pH (E, = 51.1 kcall mol) was much slower than that