Flash photolytic generation and study of ketenes: acid-catalysed hydration in aqueous solution
โ Scribed by J. Andraos; A.J. Kresge
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 601 KB
- Volume
- 57
- Category
- Article
- ISSN
- 1010-6030
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๐ SIMILAR VOLUMES
Flash photolysis of 4-diazoisochroman-3-one in aqueous solution resulted in loss of nitrogen and transient production of the a-carbonylcarbene 3-ketoisochroman-4-ylidene, the hydration of which generated a shortlived species that was identified as the enol isomer of the lactone, 4-hydroxyisochroman-
Mid infrared, far-infrared and Raman spectroscopic studies, combined with force field analyses, were performed for the hydrated platinum(II) and palladium(II) ions and cis-diammineplatinum(II) complex in acidic aqueous solutions. Simplified Density Functional Theory (DFT) calculations were made for