Photolysis of vinyl halides. Reaction of photogenerated vinyl cations with cyanate and thiocyanate ions
โ Scribed by Kitamura, Tsugio; Kobayashi, Shinjiro; Taniguchi, Hiroshi
- Book ID
- 124051849
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 625 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0022-3263
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VznyL catzons generated by the tztle photolyszs gave vznyl azades by capture of an azzde zon and thezr further photolyses resulted zn the formataon of cycloaddztzon-products vza nztrzle ylzdes derzved from the correspondznq azzrznes Recently It has been found that a vinyl catlon lntermedlate 1s form
Vinylic S N 2 Reaction of 1-Decenyliodonium Salt with Halide Ions. -Reactions of title compound (I) with tetrabutylammonium halides are examined under various conditions and the mechanistic details are investigated. In the present reaction system no sign of formation of the primary vinyl cation is