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Photolysis of vinyl bromides in the presence of tetrabutylammonium azide: trapping of a vinyl cation with azide ion

✍ Scribed by Tsugio Kitamura; Shinjiro Kobayashi; Hiroshi Taniguchi

Publisher: Elsevier Science
Year: 1979
Tongue: French
Weight: 229 KB
Volume: 20
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)93607-x

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✦ Synopsis

VznyL catzons generated by the tztle photolyszs gave vznyl azades by capture of an azzde zon and thezr further photolyses resulted zn the formataon of cycloaddztzon-products vza nztrzle ylzdes derzved from the correspondznq azzrznes Recently It has been found that a vinyl catlon lntermedlate 1s formed by photolysis of vinyl halides 1,2) However, previous studies were carried out

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