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Photolysis of the azoalkane 2,3-diazatricyclo[4.3.0.04,9]non-2-ene: Direct observation of 4-cyclohexenyldiazomethane

✍ Scribed by Waldemar Adam; Néstor Carballeira; William D. Gillaspey


Book ID
108382359
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
179 KB
Volume
24
Category
Article
ISSN
0040-4039

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✍ Waldemar Adam; William D. Gillaspey 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 243 KB

On laser photolysis of azoalkane 1 at elevated temperature, besides the expected denitrogenation into the tricyclane 2 via 1,3-diradical 2, the diazoalkane Z\_ is directly observed, denitrogenating into vinylcyclopentene 2. The bicyclo[2.2.llheptane-2,6-diyl diradical 2, in principle accessible via