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Generation and rearrangement of the 2-oxobicyclo[2.2.1]heptane-6,7-diyl diradical via nitrogen extrusion from the azoalkane 2,3-diazatricyclo[4.3.0.04,9]non-2-en-8-one

✍ Scribed by Adam, Waldemar; De Lucchi, Ottorino; Hill, Karlheinz


Book ID
118019988
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
393 KB
Volume
104
Category
Article
ISSN
0002-7863

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Competitive diradical and diazoalkane fo
✍ Waldemar Adam; William D. Gillaspey πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 243 KB

On laser photolysis of azoalkane 1 at elevated temperature, besides the expected denitrogenation into the tricyclane 2 via 1,3-diradical 2, the diazoalkane Z\_ is directly observed, denitrogenating into vinylcyclopentene 2. The bicyclo[2.2.llheptane-2,6-diyl diradical 2, in principle accessible via