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Photolysis of polystyrene in halocarbons. Evidence for the involvement of a charge-transfer interaction in the photochemical degradation

โœ Scribed by Pietro Bortolus; Francesco Minto; Silvano Lora; Mario Gleria; Giancarlo Beggiato


Book ID
116092525
Publisher
Elsevier Science
Year
1984
Weight
537 KB
Volume
4
Category
Article
ISSN
0144-2880

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Evidence for a charge-transfer mechanism
โœ Ned H. Martin; Charles W. Jefford ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 238 KB

Evidence for a charge-transfer mechanism in the photo-oxygenation of the enamine form of 1-benzyl-3,4-dihydroisoquinolines is presented. Substituent effects, normalized to constant enamine concentration, fit best a mechanism involving the formation of a rate-determining charge-transfer complex.