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Photolysis of podocarponitrile oxide and mesitonitrile oxide

โœ Scribed by George Just; Werner Zehetner

Book ID
104241115
Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
158 KB
Volume
8
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Recently, the stable 0-methyl podocarponitrile oxide(I) became _-~ readily available by oxidation of podocarpinal syn-oxime with lead tetrzacetate(l). It was of interest to us to determine whether irradiation of nitrile oxide I would lead to bridging reactions similar to those reported by ApSimon and Bdwards(l), who obtained lactax II upon irradiation of the acid aside III,

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