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Photolysis of organopolysilanes. Photochemical 1,2-silyl migration of 2-(2-phenylethenyl)- and 2-(2,2-diphenylethenyl)-substituted trisilanes

โœ Scribed by Kunai, Atsutaka; Kawakami, Toshihiro; Matsuo, Yoichi; Ishikawa, Mitsuo

Book ID
127205040
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
716 KB
Volume
11
Category
Article
ISSN
0276-7333

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Photochemical generation of tetramethyld
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โœ Yasuhiro Nakadaira; Tatsuo Otsuka; Hideki Sakurai ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 223 KB

Described herein is the first clear evidence of the photochemical generation of tetramethyldisilene which can be efficiently trapped by dienes. An intriguing 1,2-photo-induced silyl migration is also reported. Roak and Peddle have demonstrated for the first time the transient existence of reactive t