The radical cation of C6o is generated either via hole transfer from the radical cation of CCI 4 to C6o or via electron transfer from triplet C6o to CC14. The radical adduct of "CC13 to C6o, [C6oCC13]" , was also produced via two different mechanisms, namely the radical addition reaction and the rea
Photolysis of o-methylbenzophenone in the presence of C60. Facile cleavage of the CC bond connected to C60
✍ Scribed by Hideo Tomioka; Masaki Ichihashi; Katsutoshi Yamamoto
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 204 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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The character of the bond between encapsulated atoms and the enclosing C6o shell in M@C6o endohedral complexes is revisited using the density functional formalism. Mulliken population analysis indicates that this bond is strongly ionic in the case of K@C6o , predominantly covalent in the case of O@C
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