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Generation of the C60 radical cation and the radical adduct of trichloromethyl radical to C60. Pulse radiolysis and laser photolysis of C60 in CCl4

✍ Scribed by Si-de Yao; Zhi-rui Lian; Wen-feng Wang; Jia-shan Zhang; Nian-yun Lin; Hui-qi Hou; Zhen-man Zhang; Qi-zong Qinn

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
359 KB
Volume
239
Category
Article
ISSN
0009-2614

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✦ Synopsis

The radical cation of C6o is generated either via hole transfer from the radical cation of CCI 4 to C6o or via electron transfer from triplet C6o to CC14. The radical adduct of "CC13 to C6o, [C6oCC13]" , was also produced via two different mechanisms, namely the radical addition reaction and the reaction between triplet C6o and CCl4, respectively.

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The EPR spectra of CH2FC6o and CHF2C6o are presented, and the dominant conformer for each species identified. It is suggested that the equilibrium configurations of fluoromethyl-C6o radicals are determined not by steric effects, but by Coulombic interactions between highly polarizable fluorine atoms