An emission band with a mirror image pattern to the near-IR absorption band is detected for C&-produccdelectmlytically in a solution at room temperatures. The emission band reinforces our previous assignment of the absorption band. The lineshape of the ESR spectrum was reinvestigated to conclude tha
ESR and optical studies of the radical anion of C60
โ Scribed by Tatsuhisa Kato; Takeshi Kodama; Munetaka Oyama; Satoshi Okazaki; Tadamasa Shida; Takashi Nakagawa; Yoko Matsui; Shinzo Suzuki; Haruo Shiromaru; Kotaro Yamauchi; Yohji Achiba
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 393 KB
- Volume
- 186
- Category
- Article
- ISSN
- 0009-2614
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It is shown by near-IR that the anion radicals C70 and C2o are formed in vacuum by interaction between the fullerenes C70 and 1-amino-3-propanol (AP) and 1,5-diaminopentane (DAP). The temperature dependence of the ESR spectra for the systems C60-AP, CTo-AP and C7o-DAP were studied. At low temperatur
## Abstract Protonโhyperfine data are reported for the radical anions generated from azulene (1) and its alkyl derivatives 2โ11 in 1,2โdimethoxyethane both โchemicallyโ with K and electrolytically. The alkyl derivatives are 1,3โdimethylโ (2), 5,7โdimethylโ (3), 1,3,5,7โtetramethylโ (4), 2โmethylโ (
Precise electron spin resonance (ESR) spectroscopic studies have been done for KxCM). Three ESR peaks corresponding to the three important crystal phases of K,C, (face-centered cubic K&, body-centered tetragonal KJ& and body-centered cubic KJ&,) are reported. From the temperature dependencies of the