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Photolysis of desoxybenzoins in micelles, chemical yield of benzaldehyde, and magnetic isotope effect

โœ Scribed by V. F. Tarasov; E. N. Step; L. A. Margulis; A. L. Buchachenko


Book ID
112444834
Publisher
Springer
Year
1989
Tongue
English
Weight
375 KB
Volume
38
Category
Article
ISSN
1573-9171

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29Si magnetic isotope effects in the pho
โœ E.N. Step; V.F. Tarasov; A.L. Buchachenko ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 339 KB

Silicon isotope selection induced by magnetic isotope effects has been discovered in the photolysis of a silyl-containing ketone, PhCH,COSi( CH,),Ph. Silicon and carbon atom isotope selection occurs most effkiently when the photolysis is directed via the triplet radical-pair mechanism. This conclusi