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Photolysis of (arylmethyl)triphenylphosphonium salts. Substituent, counterion, and solvent effects on reaction products

โœ Scribed by Imrie, C.; Modro, T. A.; Rohwer, E. R.; Wagener, C. C. P.

Book ID
120624203
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
865 KB
Volume
58
Category
Article
ISSN
0022-3263

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## Abstract Salt effects on the reactions [Fe(CN)~6~]^4โˆ’^ + S~2~O^=^~8~ and [Ru(NH~3~)~5~py]^2+^ + S~2~O have been studied in media of different dielectric constants constituted by mixtures of water with organic cosolvents. It is known that salt and solvent effects are coupled and, consequently, ca