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Photolysis of 2,3-Diazido-2,3-dimethylbutane

✍ Scribed by Dr. Paul Margaretha; Dr. Sonja Solar

Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
120 KB
Volume
11
Category
Article
ISSN
0044-8249

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High yield in acetic acid were obtained in the by oxygen liquid-phase oxidation of 2,3-dimethylbutane at 160 "C, under 25 atm, and catalyzed by 0.64 wt % manganese. The kinetic behaviour of the products formed clears up the mechanism of oxidation. The high reactivity of the tertiary hydrogen atoms r