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Photoisomerization Reactions of Cyclopropene and 1,3,3-Trimethylcyclopropene: A Theoretical Study

✍ Scribed by Su, Ming-Der

Book ID
125910817
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
345 KB
Volume
4
Category
Article
ISSN
1549-9618

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πŸ“œ SIMILAR VOLUMES

Evidence for a carbonium ion rearrangeme
Evidence for a carbonium ion rearrangement in the reaction of triisobutylaluminum and 1,3,3-trimethylcyclopropene
✍ Herman G. Richey Jr.; Barry Kubala; Mark A. Smith πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 212 KB

Formation of acyclic products in the reaction of triisobutylaluminum and 1,3,3trimethylcyclopropene can reasonably be ascribed to a carbonium ion rearrangement. This suggestion supports the mechanism for carbalumination of alkenes proposed by Eisch.