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Photoisomerisation of (E)- to (Z)-N,N-dimethylhydrazones and thermal reversion

✍ Scribed by Clarke, Leo F.; O'Sullivan, Fiona; Hegarty, Anthony F.

Book ID
117993537
Publisher
Royal Society of Chemistry
Year
1991
Tongue
English
Weight
481 KB
Volume
11
Category
Article
ISSN
1472-779X

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πŸ“œ SIMILAR VOLUMES

Gibbs energy of activation for thermal i
Gibbs energy of activation for thermal isomerization of (1Z)-acetaldehyde hydrazone and (1Z)-acetaldehyde N,N-dimethylhydrazone by Gaussian-4 theory and CCSD(T)/CBS computations
✍ Shih-I Lu πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 166 KB

## Abstract In this article, we examined the Gibbs energy of activation for the Z/E thermal isomerization reaction of (1Z)‐acetaldehyde hydrazone and (1Z)‐acetaldehyde N,N‐dimethylhydrazone, at 298.15 K in the solvent of cyclohexane. We carried out computations employing both the Gaussian‐4 (G4) th