Photoisomerisation of bicyclo[4.2.0]octadienes to tricyclo[4.2.0.02,5] octenes: Application to the synthesis of [n]ladderanes
β Scribed by Ronald N. Warrener; Ian G. Pitt; Eric E. Nunn; Colin H.L. Kennard
- Book ID
- 104215620
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 355 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Regioselective generation of the C(2)-carbocation a of tricyc10[4.2.2.0',~]decane (1) by treatment of both corresponding epimeric alcohols 5 and 6 with BF, and trapping the rearranged tricy~lo[S.3.0.O~~~]decan-7-yl carhocation b with Et,SiH as hydride-ion donor (ionic hydrogenation) gives the corres
The reaction of photoisomerization of norbornadiene and its derivatives to the corresponding quardricyclanes, brought about either by direct irradiation or triplet sensitization is well known (1). However, similar isomerizations involving the related bicyclo[2.2.2]octa-2,5-diene system are not known
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