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Photoionization of 2,2′-bipyridine in aqueous solution

✍ Scribed by S. Dhanya; P.K. Bhattacharyya


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
272 KB
Volume
48
Category
Article
ISSN
1010-6030

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Thermal and photochemical oxidations of Fe(bpy)sz+ (bpy=2,2'-bipyridine) by the periodate anion IO,-in acidic aqueous solution were studied. For the thermal process, the rate-limiting step is monomolecular dissociation of the iron(D) complex preceding the fast oxidation by IO,-. Photo-oxidation of F