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H attack on 2,2'-bipyridine in acid aqueous solution

โœ Scribed by Sonja Solar


Publisher
Elsevier Science
Year
1985
Weight
544 KB
Volume
26
Category
Article
ISSN
0146-5724

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๐Ÿ“œ SIMILAR VOLUMES


Fluorescence behaviour of 2,2โ€ฒ-bipyridin
โœ S. Dhanya; P.K. Bhattacharyya ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 488 KB

The fluorescence behaviour of an aqueous solution of 2,2'-bipyridine (Bpy) (concentration, greater than 10m3 M) was investigated under various conditions. When complexed with Zn'+ or Cd'+ the excitation maximum changed from 365 to 370 nm and the fluorescence maximum was red shifted from 430 to 455 n

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Thermal and photochemical oxidations of Fe(bpy)sz+ (bpy=2,2'-bipyridine) by the periodate anion IO,-in acidic aqueous solution were studied. For the thermal process, the rate-limiting step is monomolecular dissociation of the iron(D) complex preceding the fast oxidation by IO,-. Photo-oxidation of F