Photoinitiation of the SRN1 reaction by excitation of charge-transfer complexes
β Scribed by Fox, Marye Anne; Younathan, Janet; Fryxell, Glen E.
- Book ID
- 121224867
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 570 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0022-3263
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## Abstract Polymerization of MMA was carried out in the presence of visible light (440 nm) with the use of Ξ³βpicolineβbromine charge transfer complex as the initiator. The rate of polymerization __R__~__p__~ increases with increasing monomer concentration and the monomer exponent was computed to b
The excited states of some. comp!excs behveen ~olycyclic somatic hydroarbons and chloranil dissoIved in polymcthylmethacrylate have been studied with a modulation excitation s-pectrophotomcter. New bands similar fo but riighffy shifted in position as compared to the Tl-Ts transition of the aromatic