The Effective Electron-Transfer Distance
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Deanna M. D’Alessandro; Peter H. Dinolfo; Joseph T. Hupp; Peter C. Junk; F. Rich
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Article
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2006
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John Wiley and Sons
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English
⚖ 242 KB
## Abstract Electroabsorption (Stark effect) measurements on the intervalence charge‐transfer (IVCT) transitions in the diastereoisomers of [{Ru(bpy)~2~}~2~(μ‐bpt^–^)]^4+^ [bpy = 2,2′‐bipyridine, bpt^–^ = 3,5‐bis(2‐pyridyl)‐1,2,4‐triazolate] in __n__‐butyronitrile glass at 77 K reveal effective cha