Photoinduced electronic energy transfer in modular, conjugated, dinuclear Ru(II)/Os(II) complexes
β Scribed by Steve Welter; Nunzio Salluce; Peter Belser; Michiel Groeneveld; Luisa De Cola
- Book ID
- 104010762
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 385 KB
- Volume
- 249
- Category
- Article
- ISSN
- 0010-8545
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β¦ Synopsis
Rigid, modular heterometallic dinuclear complexes containing luminescent units have been synthesized and their photophysical properties investigated. The metal complexes are derivatives of ruthenium and osmium trisbipyridine compounds and are linked by 2, 3, 4 or 5 paraphenylene units. A fast and efficient photoinduced energy transfer takes place from the excited ruthenium moiety to the osmium-based
π SIMILAR VOLUMES
In order to build up a multicomponent system able to perform useful light-induced functions, a dithienylethene-bridged heterodinuclear metal complex (Ru/Os) has been prepared. The compound was characterized and its photophysical properties studied in detail.