ChemInform Abstract: Photoinduced Energy and Electron Transfer Processes in Rigidly Bridged Dinuclear Ru/Os Complexes

Photoinduced Energy- and Electron-Transf

Photoinduced Energy- and Electron-Transfer Processes in Dinuclear RuII–OsII, RuII–OsIII, and RuIII–OsII Trisbipyridine Complexes Containing a Shape-Persistent Macrocyclic Spacer

✍ Margherita Venturi; Filippo Marchioni; Belén Ferrer Ribera; Vincenzo Balzani; Do 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 219 KB

## Abstract __The PF~6~__^−^ __salt of the dinuclear [(bpy)~2~Ru(1)Os(bpy)~2~]__^__4+__^ __complex, where 1 is a phenylacetylene macrocycle which incorporates two 2,2′‐bipyridine (bpy) chelating units in opposite sites of its shape‐persistent structure, was prepared. In acetonitrile solution, the R