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Photoinduced electron transfer with [Fe4S4(SC6F5)4]2−

✍ Scribed by Sumio Noda; Shigetsohi Aono; Ichiro Okura


Publisher
Elsevier Science
Year
1989
Weight
236 KB
Volume
50
Category
Article
ISSN
0304-5102

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Deoxygenation of oxiran compounds to ole
✍ Takashi Itoh; Tetsuo Nagano; Mitsuo Sato; Masaaki Hirobe 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 148 KB

The dianion complex [Fe4S4(SC6Hs)4] 2-caused deoxygenation reaction of oxiran compounds to olefins in the presence of NaBH4. The reduced form [Fe4S4(SR)4] 3-was suggested as an active reductant in this reaction.