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Photoinduced electron transfer oxidation of α-methylstyrene with molecular oxygen sensitized by dimethoxybenzenes: a non-singlet-oxygen mechanism

✍ Scribed by Tadashi Mori; Makoto Takamoto; Yoshimasa Tate; Junya Shinkuma; Takehiko Wada; Yoshihisa Inoue


Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
101 KB
Volume
42
Category
Article
ISSN
0040-4039

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Photoinduced Electron-Transfer Oxidation
✍ Tadashi Mori; Makoto Takamoto; Takehiko Wada; Yoshihisa Inoue 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 177 KB 👁 2 views

Dedicated to Professor Andre M. Braun on the occasion of his 60th birthday a-Methylstyrene (1) was photo-oxidized in the presence of a series of alkylated dimethoxybenzenes as sensitizers in an oxygen-saturated MeCN solution to afford the cleaved ketone 2, epoxide 3, as well as a small amount of th